Modulating guest binding in sulfonylcalixarene-based metal-organic supercontainers

被引:57
作者
Dai, Feng-Rong [1 ]
Becht, Dustin C. [1 ]
Wang, Zhenqiang [1 ]
机构
[1] Univ S Dakota, Dept Chem, Churchill Haines Labs, Vermillion, SD 57069 USA
基金
美国国家科学基金会;
关键词
MOLECULAR FLASKS; CHEMISTRY; COMPLEX; METALLACYCLES; REACTIVITY; POLYHEDRA; CATALYSIS; CLUSTER; DESIGN; LIGAND;
D O I
10.1039/c3cc47420h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-organic supercontainers (MOSCs) represent a new family of synthetic receptors derived from container precursors and featuring both endo and exo cavities. A neutral MOSC has been functionalized into an anionic container by incorporating sulfo groups. The anionic MOSC exhibits cavity-specific binding properties in both solid state and solution.
引用
收藏
页码:5385 / 5387
页数:3
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