Modular Assembly of Metal-Organic Supercontainers Incorporating Sulfonylcalixarenes

被引：150

作者：

Dai, Feng-Rong ^{[1
]}

Wang, Zhenqiang ^{[1
]}

机构：

[1] Univ S Dakota, Dept Chem, Churchill Haines Labs, Vermillion, SD 57069 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 19期

关键词：

COORDINATION CHEMISTRY; MOLECULAR CAPSULE; HYDROGEN-BONDS; CAGES; RECOGNITION; COMPLEXES; SYSTEMS; CLUSTER; IONS;

D O I：

10.1021/ja300095j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new strategy for the design of container molecules is presented. Sulfonylcalix[4]arenes, which are synthetic macrocyclic containers, are used as building blocks that are combined with various metal ions and tricarboxylate ligands to construct metal organic "supercontainers" (MOSCs). These MOSCs possess both endo and exo cavities and thus mimic the structure of viruses. The synthesis of MOSCs is highly modular, robust, and predictable. The unique features of MOSCs are expected to provide exciting new opportunities for the exploration of their functional applications.

引用

页码：8002 / 8005

页数：4

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