Spatially heterogeneous dynamics and dynamic facilitation in a model of viscous silica

被引:103
作者
Vogel, M
Glotzer, SC
机构
[1] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
关键词
D O I
10.1103/PhysRevLett.92.255901
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We perform molecular dynamics simulations to study the structural relaxation dynamics of a model of viscous silica, the prototype of a strong glass former. We find that the melt dynamics are spatially heterogeneous regardless of whether the bulk relaxation is non-Arrhenius or Arrhenius, and cannot be understood as a statistical bondbreaking process. Further, we show that stringlike motion is suppressed by the covalent bondings, yet high particle mobility propagates continuously, supporting the concept of dynamic facilitation emphasized in recent theoretical work.
引用
收藏
页码:255901 / 1
页数:4
相关论文
共 34 条
  • [1] ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS
    ADAM, G
    GIBBS, JH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (01) : 139 - &
  • [2] Polymer-specific effects of bulk relaxation and stringlike correlated motion in the dynamics of a supercooled polymer melt
    Aichele, M
    Gebremichael, Y
    Starr, FW
    Baschnagel, J
    Glotzer, SC
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (10) : 5290 - 5304
  • [3] RELAXATION IN LIQUIDS, POLYMERS AND PLASTIC CRYSTALS - STRONG FRAGILE PATTERNS AND PROBLEMS
    ANGELL, CA
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 131 : 13 - 31
  • [4] A strong to fragile transition in a model of liquid silica
    Barrat, JL
    Badro, J
    Gillet, P
    [J]. MOLECULAR SIMULATION, 1997, 20 (1-2) : 17 - 25
  • [5] Growing range of correlated motion in a polymer melt on cooling towards the glass transition
    Bennemann, C
    Donati, C
    Baschnagel, J
    Glotzer, SC
    [J]. NATURE, 1999, 399 (6733) : 246 - 249
  • [6] DIFFUSION OF SILICON IN AMORPHOUS SILICA
    BREBEC, G
    SEGUIN, R
    SELLA, C
    BEVENOT, J
    MARTIN, JC
    [J]. ACTA METALLURGICA, 1980, 28 (03): : 327 - 333
  • [7] Spatial correlations of mobility and immobility in a glass-forming Lennard-Jones liquid
    Donati, C
    Glotzer, SC
    Poole, PH
    Kob, W
    Plimpton, SJ
    [J]. PHYSICAL REVIEW E, 1999, 60 (03) : 3107 - 3119
  • [8] Stringlike cooperative motion in a supercooled liquid
    Donati, C
    Douglas, JF
    Kob, W
    Plimpton, SJ
    Poole, PH
    Glotzer, SC
    [J]. PHYSICAL REVIEW LETTERS, 1998, 80 (11) : 2338 - 2341
  • [9] Spatially heterogeneous dynamics in supercooled liquids
    Ediger, MD
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2000, 51 : 99 - 128
  • [10] KINETIC ISING-MODEL OF THE GLASS-TRANSITION
    FREDRICKSON, GH
    ANDERSEN, HC
    [J]. PHYSICAL REVIEW LETTERS, 1984, 53 (13) : 1244 - 1247