Green chemistry at work:: from "LAS (linear alkylbenzenesulphonic acids) waste" to fine chemicals by iron/O2 oxidation

被引：8

作者：

Cuzzola, A

Bernini, M

Salvadori, P ^{[1
]}

机构：

[1] CNR, Ist Chim Composti Organo Met, Sez Pisa, Pisa, Italy

[2] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2004年 / 52卷 / 02期

关键词：

surfactant degradation; iron catalysts; molecular oxygen;

D O I：

10.1016/j.apcatb.2004.03.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular oxygen was investigated as sustainable oxidant for the degradation of LAS (linear alkylbenzenesulphonic acids) in the presence of homogeneous and heterogeneous iron based catalysts. The influence of temperature, oxygen pressure and substrate/catalyst molar ratio on the degree of mineralization and LAS conversion was considered. Molecular oxygen showed an interesting behaviour as selective oxidant: the conversion to CO2 was low in all cases and the formation of useful partial oxidation products was observed. The applicability of the process to convert a waste product in fine chemicals was evaluated. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：117 / 122

页数：6

共 31 条

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