Synthesis and characterization of isomanolonitrile dithiolato palladium complexes. Crystal structure of (PPh3)(2)Pd(S2C4N2) and (Et4N)(2)WS4Pd(S2C4N2)

被引：6

作者：

Long, DL

Zheng, H

Xin, XQ

Sakane, G

Shibahara, T

机构：

[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,INST COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

[2] OKAYAMA UNIV SCI,DEPT CHEM,OKAYAMA 700,JAPAN

来源：

POLYHEDRON | 1997年 / 16卷 / 24期

关键词：

synthesis; crystal structure; palladium; dithiolate; coordination compounds; substitution reaction;

D O I：

10.1016/S0277-5387(97)00213-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of isomalononitrile dithiolato palladium complexes, (PPh3)(2)Pd(i-mnt) (1), [P(OPh)(3)](2)Pd(i-mnt) (2), (PPh3)(py)Pd(i-mnt). CH3CN (3), (Et4N)(2)Pd(i-mnt)(2) (4) and (Ph4As)(2)Pd(i-mnt)(2) (5) were synthesized and characterized by elemental analysis and IR spectroscopy. The reaction between (Et4N)(2)Pd(i-mnt)(2) (4) and (Et4N)(2)WS4 gave a mixed metal cluster (Et4N)(2)WS4Pd(i-mnt) (6). The crystallographically determined structures of 1 and 6 are reported. (C) 1997 Elsevier Science Ltd.

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页码：4305 / 4311

页数：7

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