Dimerization and oligomerization of ethylene catalyzed by a palladium(II) complex with imine-phosphine ligand

被引：13

作者：

Chen, JT ^{[1
]}

Liu, ST ^{[1
]}

Zhao, KQ ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2000年 / 47卷 / 01期

关键词：

ethylene; dimerization; palladium; iminephosphine;

D O I：

10.1002/jccs.200000035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-iminophosphine complex [Pd(P-N)(CH3)Cl] (P-N = o-diphenyl-phosphino-N-benzaldimine) has been found to be a catalyst for dimerization and trimerization of ethylene. Some mechanistic insight concerning this oligomerization is discussed.

引用

页码：279 / 281

页数：3

共 10 条

[1] ORGANIC REACTIONS INVOLVING TRANSITION METALS .3. PALLADIUM(II)-CATALYSED DIMERIZATION OF OLEFINIC COMPOUNDS [J].

BARLOW, MG ;

BRYANT, MJ ;

HASZELDI.RN ;

MACKIE, AG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 21 (01) :215-&

[2] DIMERIZATION OF ETHYLENE USING PALLADOUS CHLORIDE AS CATALYST [J].

KUSUNOKI, Y ;

KATSUNO, R ;

HASEGAWA, N ;

KUREMATS.S ;

NAGAO, Y ;

ISHII, K ;

TSUTSUMI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1966, 39 (09) :2021-+

[3] Cationic palladium eta(3)-allyl complexes with hemilabile P,O-ligands: Synthesis and reactivity. Insertion of ethylene into the Pd-allyl function [J].

Mecking, S ;

Keim, W .

ORGANOMETALLICS, 1996, 15 (11) :2650-2656

[4] DIMERIZATION OF ETHYLENE AND PROPYLENE CATALYZED BY TRANSITION-METAL COMPLEXES [J].

PILLAI, SM ;

RAVINDRANATHAN, M ;

SIVARAM, S .

CHEMICAL REVIEWS, 1986, 86 (02) :353-399

[5] New imine-phosphine palladium complexes catalyze copolymerization of CO-ethylene and CO-norbornylene and provide well-characterized stepwise insertion intermediates of various unsaturated substrates [J].

Reddy, KR ;

Chen, CL ;

Liu, YH ;

Peng, SM ;

Chen, JT ;

Liu, ST .

ORGANOMETALLICS, 1999, 18 (14) :2574-2576

[6] An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes [J].

Shirakawa, E ;

Yoshida, H ;

Takaya, H .

TETRAHEDRON LETTERS, 1997, 38 (21) :3759-3762

[7] Carbostannylation of alkynes catalyzed by an iminophosphine-palladium complex [J].

Shirakawa, E ;

Yoshida, H ;

Kurahashi, T ;

Nakao, Y ;

Hiyama, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2975-2976

[8] Olefin carbonylation catalysis with cationic palladium complexes: Selectivity and possible intermediates [J].

Sperrle, M ;

Consiglio, G .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (11) :1557-1565

[9] Isotactic and atactic copolymerization of styrene and carbon monoxide using cationic palladium-phosphino(dihydrooxazole) complexes [J].

Sperrle, M ;

Aeby, A ;

Consiglio, G ;

Pfaltz, A .

HELVETICA CHIMICA ACTA, 1996, 79 (05) :1387-1392

[10] Oligomerisation of ethene by new palladium iminophosphine catalysts [J].

van den Beuken, EK ;

Smeets, WJJ ;

Spek, AL ;

Feringa, BL .

CHEMICAL COMMUNICATIONS, 1998, (02) :223-224

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