2-functionalized allyl tris(trimethylsilyl)silanes as radical-based allylating agents

被引：33

作者：

Chatgilialoglu, C

Ferreri, C

Ballestri, M

Curran, DP

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

[2] UNIV NAPLES,DIPARTIMENTO CHIM ORGAN & BIOL,I-80134 NAPLES,ITALY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(96)01354-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical allylations with 2-functionalized allyl tris(trimethylsilyl)silanes occur under mild conditions in good to excellent yield provided that the radical precursor and the silane have the appropriate electronic pairing. These reactions offer tin-free alternatives for tansformations that are currently conducted with allylstannanes. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：6387 / 6390

页数：4

共 24 条

[1] REACTIONS OF A GLYCIDYL RADICAL EQUIVALENT WITH 2-FUNCTIONALIZED ALLYL STANNANES [J].