Nickel(0)-catalyzed asymmetric cross-coupling reactions of allylic compounds with arylboronic acids

被引：83

作者：

Chung, KG ^{[1
]}

Miyake, Y ^{[1
]}

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 01期

关键词：

D O I：

10.1039/a908076g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active oxazolinylferrocenylphosphines have been found to work quite effectively as chiral ligands in nickel(0)-catalyzed cross-coupling reactions of allylic compounds with arylboronic acids, which are known to behave as "hard" nucleophiles. The expected coupling products have been obtained in good yields with moderate enantioselectivities (up to 53% ee). This is the first example of asymmetric allylic substitution using organoboron compounds.

引用

页码：15 / 18

页数：4

共 42 条

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