Dual Templating Synthesis of Mesoporous Titanium Nitride Microspheres

被引:75
作者
Bang, Jin Ho [1 ]
Suslick, Kenneth S. [1 ]
机构
[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA
关键词
ULTRASONIC SPRAY-PYROLYSIS; SILICA PARTICLES; MACROPOROUS MONOLITHS; POROUS MATERIALS; SURFACE-AREA; METAL-OXIDES; PORE-SIZE; SOL-GEL; NANOPARTICLES; CATALYST;
D O I
10.1002/adma.200802309
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchically nanostructured titanium nitride is prepared via a novel and facile in situ dual templating approach. No prestructured templates are necessary; instead, a template is generated in situ during the synthesis from a liquid core and the resulting spherical shell, and the template is removed in the final heating without any additional chemical etching.
引用
收藏
页码:3186 / +
页数:6
相关论文
共 60 条
[11]   Nanocrystalline TiN derived by a two-step halide approach for electrochemical capacitors [J].
Choi, Daiwon ;
Kumta, Prashant N. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (12) :A2298-A2303
[12]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[13]  
DRYGAS M, 2003, ADV MATER, V15, P1012
[14]   Two-stage aerosol synthesis of titanium nitride TiN and titanium oxynitride TiOxNy nanopowders of spherical particle morphology [J].
Drygas, Mariusz ;
Czosnek, Cezary ;
Paine, Robert T. ;
Janik, Jerzy F. .
CHEMISTRY OF MATERIALS, 2006, 18 (13) :3122-3129
[15]   THERMODYNAMICS OF TERNARY NITRIDE FORMATION BY AMMONOLYSIS - APPLICATION TO LIMON2, NA3WN3, AND NA3WO3N [J].
ELDER, SH ;
DISALVO, FJ ;
TOPOR, L ;
NAVROTSKY, A .
CHEMISTRY OF MATERIALS, 1993, 5 (10) :1545-1553
[16]  
Farrusseng D, 2001, ANGEW CHEM INT EDIT, V40, P4204, DOI 10.1002/1521-3773(20011119)40:22<4204::AID-ANIE4204>3.0.CO
[17]  
2-D
[18]   Growth confined by the nitrogen source: Synthesis of pure metal nitride nanoparticles in mesoporous graphitic carbon nitride [J].
Fischer, Anna ;
Antonietti, Markus ;
Thomas, Arne .
ADVANCED MATERIALS, 2007, 19 (02) :264-+
[19]   Single-crystal gallium nitride nanotubes [J].
Goldberger, J ;
He, RR ;
Zhang, YF ;
Lee, SW ;
Yan, HQ ;
Choi, HJ ;
Yang, PD .
NATURE, 2003, 422 (6932) :599-602
[20]   Morphology of titania coatings on silica gel [J].
Hanprasopwattana, A ;
Rieker, T ;
Sault, AG ;
Datye, AK .
CATALYSIS LETTERS, 1997, 45 (3-4) :165-175