A general method for the formation of diaryl selenides using copper(I) catalysts

被引：108

作者：

Gujadhur, RK ^{[1
]}

Venkataraman, D ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(02)02480-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a mild, palladium-free synthetic protocol for the cross coupling reaction of aryl iodides and phenyl selenol using 10 mol% CuI/neocuproine, NaOt-Bu or K2CO3 as base, in toluene, at 110degreesC. Using this protocol, we show that a variety of diaryl selenides can be synthesized in good yields from commercially available aryl iodides. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：81 / 84

页数：4

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