Synthesis of silver nanocrystallites by a new thermal decomposition method and their characterization

被引：70

作者：

Lee, DK ^{[1
]}

Kang, YS ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Chem, Pusan, South Korea

来源：

ETRI JOURNAL | 2004年 / 26卷 / 03期

关键词：

silver nanoparticle; thermal decomposition; silver-oleate complex;

D O I：

10.4218/etrij.04.0103.0061

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

We formed silver nanocrystallites by the thermal decomposition of a Ag+1-oleate complex, which was prepared by a reaction with AgNO3 and sodium oleate in a water solution. The resulting monodispersed silver nanocrystallites were produced by controlling the temperature (290 degreesC). Transmission electron microscopic (TEM) images of the particles showed a 2-dimensional assembly of the particles with a diameter of 9.5 +/- 0.7 nm, demonstrating the uniformity of these nanocrystallites. An energy-dispersive X-ray (EDX-) spectrum and X-ray diffraction (XRD) peaks of the nanocrystallites showed the highly crystalline nature of the silver structure. We analyzed the decomposition of the Ag+1-oleate complex using a Thermo Gravimetric Analyzer (TGA) and observed the crystallization process using XRD.

引用

页码：252 / 256

页数：5

共 16 条

[11] Electrical transport studies of Ag nanoclusters embedded in glass matrix [J].