Pressure-induced transition from localized electron toward band antiferromagnetism in LaMnO3 -: art. no. 087201

被引:60
作者
Zhou, JS [1 ]
Goodenough, JB [1 ]
机构
[1] Univ Texas, Texas Mat Inst, Austin, TX 78712 USA
关键词
D O I
10.1103/PhysRevLett.89.087201
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The temperature dependence of the ac susceptibility under pressure has been used to track the Neel temperature T-N of the Mott insulators LaMnO3, CaMnO3, and YCrO3. Bloch's rule relating T-N to volume V, viz., alpha=dlogT(N)/dlogV=-3.3, is obeyed in YCrO3 and CaMnO3; it fails in LaMnO3. This breakdown is interpreted to be due to a sharp increase in the factor [U-1+(2Delta)(-1)] entering the superexchange perturbation formula. A first-order change at 7 kbar indicates that the transition from localized-electron to band magnetism is not smooth.
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