Recrystallization kinetics and glass transition of rice starch gel system

被引:100
作者
Baik, MY [1 ]
Kim, KJ [1 ]
Cheon, KC [1 ]
Ha, YC [1 ]
Kim, WS [1 ]
机构
[1] AGCY DEF DEV, FOOD DIV, TAEJON 305600, SOUTH KOREA
关键词
recrystallization; glass transition; rice starch gel; nucleation; propagation; Avrami equation; Arrhenius equation;
D O I
10.1021/jf960713u
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The effect of storage temperature on recrystallization and glass transition temperature (T-g) Of nonwaxy and waxy rice starch gel systems containing 60% moisture content was investigated by differential scanning calorimetry to understand the relationship between them. The nucleation and propagation for the recrystallization process were determined by recrystallization degree obtained from crystallite melting enthalpy changes during storage. The recrystallization rate for both rice starch gels within 3 days of storage and its temperature dependence were analyzed by Avrami and Arrhenius equations. The maximum nucleation and propagation for recrystallization of both rice starch gel systems occurred at 4 degrees C and 30 degrees C, respectively. The T-g slightly increased with increasing recrystallization degree, and the highest T-g was observed in the maximum recrystallization temperature ranges. The T-g and recrystallization rate of nonwaxy rice starch gel were changed more than those of the waxy one, while the higher activation energy and Q(10) value were shown in waxy rice starch gel.
引用
收藏
页码:4242 / 4248
页数:7
相关论文
共 45 条
[1]  
ABLETT S, 1986, CHEM PHYSICS BAKING, P30
[2]   STUDY OF DIFFUSION AND PERMEATION OF GASES IN UNDRAWN AND UNIAXIALLY DRAWN FILMS MADE FROM POTATO AND RICE STARCH CONDITIONED AT DIFFERENT RELATIVE HUMIDITIES [J].
ARVANITOYANNIS, I ;
KALICHEVSKY, M ;
BLANSHARD, JMV ;
PSOMIADOU, E .
CARBOHYDRATE POLYMERS, 1994, 24 (01) :1-15
[3]   Edible films made from sodium caseinate, starches, sugars or glycerol .1. [J].
Arvanitoyannis, I ;
Psomiadou, E ;
Nakayama, A .
CARBOHYDRATE POLYMERS, 1996, 31 (04) :179-192
[4]   RATES OF CRYSTALLIZATION OF DRIED LACTOSE-SUCROSE MIXTURES [J].
ARVANITOYANNIS, I ;
BLANSHARD, JMV .
JOURNAL OF FOOD SCIENCE, 1994, 59 (01) :197-205
[5]  
ATWELL WA, 1988, CEREAL FOOD WORLD, V33, P306
[6]  
BILIADERIS CG, 1992, FOOD TECHNOL-CHICAGO, V46, P98
[7]   THERMAL CHARACTERIZATION OF RICE STARCHES - A POLYMERIC APPROACH TO PHASE-TRANSITIONS OF ANTIGRANULOCYTES STARCH [J].
BILIADERIS, CG ;
PAGE, CM ;
MAURICE, TJ ;
JULIANO, BO .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1986, 34 (01) :6-14
[8]   INFLUENCE OF LIPIDS ON THE THERMAL AND MECHANICAL-PROPERTIES OF CONCENTRATED STARCH GELS [J].
BILIADERIS, CG ;
TONOGAI, JR .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1991, 39 (05) :833-840
[9]  
BILIADERIS CG, 1991, ADV EXP MED BIOL, P251
[10]   RHEOLOGICAL STUDIES OF AQUEOUS AMYLOSE GELS - THE EFFECT OF CHAIN-LENGTH AND CONCENTRATION ON GEL MODULUS [J].
CLARK, AH ;
GIDLEY, MJ ;
RICHARDSON, RK ;
ROSSMURPHY, SB .
MACROMOLECULES, 1989, 22 (01) :346-351