Solution-Processed, Molecular Photovoltaics that Exploit Hole Transfer from Non-Fullerene, n-Type Materials

被引:78
作者
Douglas, Jessica D. [1 ,2 ,3 ]
Chen, Mark S. [1 ,2 ,3 ]
Niskala, Jeremy R. [1 ,2 ,3 ]
Lee, Olivia P. [1 ,2 ,3 ]
Yiu, Alan T. [1 ,2 ,3 ]
Young, Eric P. [1 ,2 ]
Frechet, Jean M. J. [1 ,2 ,3 ,4 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] King Abdullah Univ Sci & Technol, Thuwal 239556900, Saudi Arabia
关键词
ORGANIC SOLAR-CELLS; OPEN-CIRCUIT VOLTAGE; BULK-HETEROJUNCTION; ELECTRON-TRANSFER; FILM MORPHOLOGY; PERFORMANCE; ACCEPTOR; EFFICIENCY; DYNAMICS; DONOR;
D O I
10.1002/adma.201305444
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solution-processed organic photovoltaic devices containing p-type and non-fullerene n-type small molecules obtain power conversion efficiencies as high as 2.4%. The optoelectronic properties of the n-type material BT(TTI-n12)(2) allow these devices to display high open-circuit voltages (>0.85 V) and generate significant charge carriers through hole transfer in addition to the electron-transfer pathway, which is common in fullerene-based devices.
引用
收藏
页码:4313 / 4319
页数:7
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