Sr9Ni6.64O21: A new member (n=2) of the perovskite-related A(3n+3)A'nB3+nO9+6n family

被引：37

作者：

Campa, J

GutierrezPuebla, E

Monge, A

Rasines, I

RuizValero, C

机构：

[1] CSIC,INST CIENCIA MAT MADRID,E-28049 MADRID,SPAIN

[2] UNIV COMPLUTENSE MADRID,FAC CIENCIAS GEOL,E-28040 MADRID,SPAIN

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 126卷 / 01期

关键词：

D O I：

10.1006/jssc.1996.0305

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of a new phase Sr9Ni6.64O21 were grown. This compound is the n = 2 member of the A(3n+3)A(n)'Bn+3O6n+9 series. The composition and the crystal structure have been established from X-ray single crystal diffraction data, The structure contains face-shared chains of NiO6 polyhedra parallel to the c axis and is related with the hexagonal 2H polytype perovskite, Sr9Ni6.64O21 crystallizes in the space group R(3) over barc$ (No. 167) with a = 9.467(2) Angstrom, c = 35.87(5) Angstrom, V = 2784.(4) Angstrom(3), and Z = 6. A comparison is made between the structure of the title compound and the other members of the series. (C) 1996 Academic Press, Inc.

引用

页码：27 / 32

页数：6

共 12 条

[1] CRUCIAL INTERPLAY OF ORBITAL AND CATION ANION INTERACTIONS IN THE SOLID-STATE - DISTORTIONS OF NIO6 OCTAHEDRA IN BANILN2O5 OXIDES [J].