Simply Mixed Commercial Red Phosphorus and Carbon Nanotube Composite with Exceptionally Reversible Sodium-Ion Storage

被引：408

作者：

Li, Wei-Jie ^{[1
]}

Chou, Shu-Lei ^{[1
]}

Wang, Jia-Zhao ^{[1
]}

Liu, Hua-Kun ^{[1
]}

Dou, Shi-Xue ^{[1
]}

机构：

[1] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia

来源：

NANO LETTERS | 2013年 / 13卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

Commercial red phosphorus; carbon nanotube network; reversible cycle; sodium ion battery; CAPACITY ANODE MATERIALS; LITHIUM-ION; RATE CAPABILITY; LOW-COST; BATTERIES; ELECTRODES; INSERTION; CATHODE; NANOCOMPOSITES; NANOWIRES;

D O I：

10.1021/nl403053v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently, sodium ion batteries (SIBs) have been given intense attention because they are the most promising alternative to lithium ion batteries for application in renewable power stations and smart grid, owing to their low cost, their abundant natural resources, and the similar chemistry of sodium and lithium. Elemental phosphorus (P) is the most promising anode materials for SIBs with the highest theoretical capacity of 2596 mA h g(-1), but the commercially available red phosphorus cannot react with Na reversibly. Here, we report that simply hand-grinding commercial microsized red phosphorus and carbon nanotubes (CNTs) can deliver a reversible capacity of 1675 mA h g(-1) for sodium ion batteries (SIBs), with capacity retention of 76.6% over 10 cycles. Our results suggest that the simply mixed commercial red phosphorus and CNTs would be a promising anode candidate for SIBs with a high capacity and low cost.

引用

页码：5480 / 5484

页数：5

共 37 条

[11]

Lee SW, 2010, NAT NANOTECHNOL, V5, P531, DOI [10.1038/NNANO.2010.116, 10.1038/nnano.2010.116]

[12] Prussian blue: a new framework of electrode materials for sodium batteries [J].

Lu, Yuhao ;

Wang, Long ;

Cheng, Jinguang ;

Goodenough, John B. .

CHEMICAL COMMUNICATIONS, 2012, 48 (52) :6544-6546

[13] Nanoconfined phosphorus in mesoporous carbon as an electrode for Li-ion batteries: performance and mechanism [J].

Marino, C. ;

Boulet, L. ;

Gaveau, P. ;

Fraisse, B. ;

Monconduit, L. .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (42) :22713-22720

[14] Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials [J].

Ong, Shyue Ping ;

Chevrier, Vincent L. ;

Hautier, Geoffroy ;

Jain, Anubhav ;

Moore, Charles ;

Kim, Sangtae ;

Ma, Xiaohua ;

Ceder, Gerbrand .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3680-3688

[15] Na-ion batteries, recent advances and present challenges to become low cost energy storage systems [J].

Palomares, Veronica ;

Serras, Paula ;

Villaluenga, Irune ;

Hueso, Karina B. ;

Carretero-Gonzalez, Javier ;

Rojo, Teofilo .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :5884-5901

[16] Black phosphorus and its composite for lithium rechargeable batteries [J].

Park, Cheol-Min ;

Sohn, Hun-Joon .

ADVANCED MATERIALS, 2007, 19 (18) :2465-+

[17] Nanostructured SnSb/carbon nanotube composites synthesized by reductive precipitation for lithium-ion batteries [J].

Park, Min-Sik ;

Needham, Scott A. ;

Wang, Guo-Xiu ;

Kang, Yong-Mook ;

Park, Jin-Soo ;

Dou, Shi-Xue ;

Liu, Hua-Kun .

CHEMISTRY OF MATERIALS, 2007, 19 (10) :2406-2410

[18] Nanosized Na4Fe(CN)6/C Composite as a Low-Cost and High-Rate Cathode Material for Sodium-Ion Batteries [J].

Qian, Jianfeng ;

Zhou, Min ;

Cao, Yuliang ;

Ai, Xinping ;

Yang, Hanxi .

ADVANCED ENERGY MATERIALS, 2012, 2 (04) :410-414

[19] High Capacity and Rate Capability of Amorphous Phosphorus for Sodium Ion Batteries [J].

Qian, Jiangfeng ;

Wu, Xianyong ;

Cao, Yuliang ;

Ai, Xinping ;

Yang, Hanxi .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (17) :4633-4636

[20] High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries [J].

Qian, Jiangfeng ;

Chen, Yao ;

Wu, Lin ;

Cao, Yuliang ;

Ai, Xinping ;

Yang, Hanxi .

CHEMICAL COMMUNICATIONS, 2012, 48 (56) :7070-7072

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