Tailor-Made Hybrid Organic-Inorganic Porous Materials Based on Polyhedral Oligomeric Silsesquioxanes (POSS) by the Step-Growth Mechanism of Thiol-Ene "Click" Chemistry

被引：102

作者：

Alves, Filipa ^{[1
]}

Nischang, Ivo ^{[1
]}

机构：

[1] Johannes Kepler Univ Linz, Inst Polymer Chem, A-4060 Leonding, Austria

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 51期

基金：

奥地利科学基金会;

关键词：

click chemistry; grafting; hybrid monolith; polyhedral oligomeric silsesquioxanes; polymerization; CAPILLARY LIQUID-CHROMATOGRAPHY; RING-OPENING POLYMERIZATION; CUBIC SILOXANE CAGES; HIGH-SURFACE-AREA; MONOLITHIC COLUMNS; NETWORKS; POLYMERS; BLOCKS; PHOTOPOLYMERIZATION; FACILE;

D O I：

10.1002/chem.201303759

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Clicking 3D materials: Hybrid, organic-inorganic polyhedral oligomeric silsesquioxane precursors are woven into macroscopically shaped entities by thiol-ene chemistry in a radical-mediated, step-growth fashion, by photo or thermal initiation (see figure). The materials are nanostructured and their macroporous features and physical properties are easily tailored. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：17310 / 17313

页数：4

共 40 条

[1]

Conceptual Design of Large Surface Area Porous Polymeric Hybrid Media Based on Polyhedral Oligomeric Silsesquioxane Precursors: Preparation, Tailoring of Porous Properties, and Internal Surface Functionalization [J].

Alves, Filipa ;

Scholder, Pascal ;

Nischang, Ivo .

ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (07) :2517-2526

[2]

[Anonymous], 2010, ANGEW CHEM INT ED, V49, P1540

[3]

[Anonymous], 2001, ANGEW CHEM INT ED, V40, P2004

[4]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P4592

[5]

[Anonymous], 2010, Angew. Chem, V122, P1584, DOI DOI 10.1002/ANGE.200903924

[6]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P60

[7]

"Clicking" Polymers or Just Efficient Linking: What Is the Difference? [J].

Barner-Kowollik, Christopher ;

Du Prez, Filip E. ;

Espeel, Pieter ;

Hawker, Craig J. ;

Junkers, Tanja ;

Schlaad, Helmut ;

Van Camp, Wim .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (01) :60-62

[8]

Porous Siloxane-Organic Hybrid with Ultrahigh Surface Area through Simultaneous Polymerization-Destruction of Functionalized Cubic Siloxane Cages [J].

Chaikittisilp, Watcharop ;

Kubo, Masaru ;

Moteki, Takahiko ;

Sugawara-Narutaki, Ayae ;

Shimojima, Atsushi ;

Okubo, Tatsuya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (35) :13832-13835

[9]

Hybrid Porous Materials with High Surface Area Derived from Bromophenylethenyl-Functionalized Cubic Siloxane-Based Building Units [J].

Chaikittisilp, Watcharop ;

Sugawara, Ayae ;

Shimojima, Atsushi ;

Okubo, Tatsuya .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (20) :6006-6014

[10]

Thiol-ene photopolymerization mechanism and rate limiting step changes for various vinyl functional group chemistries [J].

Cramer, NB ;

Reddy, SK ;

O'Brien, AK ;

Bowman, CN .

MACROMOLECULES, 2003, 36 (21) :7964-7969

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