Surface science studies of gas sensing materials:: SnO2

被引:187
作者
Batzill, Matthias [1 ]
机构
[1] Univ S Florida, Dept Phys, Tampa, FL 33620 USA
关键词
surface science; single crystal; metal oxide surfaces; photoemission; scanning tunneling microscopy;
D O I
10.3390/s6101345
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This review is an attempt to give an overview on how surface science studies can contribute to a fundamental understanding of metal oxide gas sensors. In here tin dioxide is used as a model system for metal oxide gas sensor materials and we review surface science studies of single crystal SnO2. The composition, structure, electronic and chemical properties of the ( 110) and ( 101) surfaces is described. The influence of compositional changes as a function of the oxygen chemical potential on the electronic surface structure and the chemical properties is emphasized on the example of the ( 101) surface. The surface chemical properties are discussed on the example of water adsorption. It is shown the chemical and gas sensing properties depend strongly on the surface composition.
引用
收藏
页码:1345 / 1366
页数:22
相关论文
共 65 条
[21]   OXYGEN VACANCIES AND DEFECT ELECTRONIC STATES ON THE SNO2(110)-1X1 SURFACE [J].
COX, DF ;
FRYBERGER, TB ;
SEMANCIK, S .
PHYSICAL REVIEW B, 1988, 38 (03) :2072-2083
[22]   SURFACE-PROPERTIES OF CLEAN AND GAS-DOSED SNO2(110) [J].
COX, DF ;
FRYBERGER, TB ;
ERICKSON, JW ;
SEMANCIK, S .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1987, 5 (04) :1170-1171
[23]   Ultra-long single crystalline nanoribbons of tin oxide [J].
Dai, ZR ;
Pan, ZW ;
Wang, ZL .
SOLID STATE COMMUNICATIONS, 2001, 118 (07) :351-354
[24]   INFLUENCE OF THE SURFACE RECONSTRUCTION ON THE WORK FUNCTION AND SURFACE CONDUCTANCE OF (110)SNO2 [J].
DEFRESART, E ;
DARVILLE, J ;
GILLES, JM .
APPLICATIONS OF SURFACE SCIENCE, 1982, 11-2 (JUL) :637-651
[25]   The surface science of titanium dioxide [J].
Diebold, U .
SURFACE SCIENCE REPORTS, 2003, 48 (5-8) :53-229
[26]   TEMPERATURE PROGRAMMED DESORPTION STUDY OF WATER ADSORBED ON METAL-OXIDES .1. ANATASE AND RUTILE [J].
EGASHIRA, M ;
KAWASUMI, S ;
KAGAWA, S ;
SEIYAMA, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (11) :3144-3149
[27]  
EGASHIRA M, 1981, J PHYS CHEM-US, V85, P4125, DOI 10.1021/j150626a034
[28]   OXYGEN DEFICIENT SNO2(110) AND TIO2(110) - A COMPARATIVE-STUDY BY PHOTOEMISSION [J].
EGDELL, RG ;
ERIKSEN, S ;
FLAVELL, WR .
SOLID STATE COMMUNICATIONS, 1986, 60 (10) :835-838
[29]   WATER-ADSORPTION ON STOICHIOMETRIC AND DEFECTIVE SNO2(110) SURFACES [J].
GERCHER, VA ;
COX, DF .
SURFACE SCIENCE, 1995, 322 (1-3) :177-184
[30]   FORMIC-ACID DECOMPOSITION ON SNO2(110) [J].
GERCHER, VA ;
COX, DF .
SURFACE SCIENCE, 1994, 312 (1-2) :106-114