Models for the reactive states of homocuprates:: syntheses, structures and reactivities of [Cu2Li2Mes4] and Cu3LiMes4]

被引：33

作者：

Davies, Robert P. ^{[1
]}

Hornauer, Stefan ^{[1
]}

White, Andrew J. P. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci & Technol, Dept Chem, London SW7 2AZ, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 03期

关键词：

D O I：

10.1039/b612554a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterisation of two novel tetranuclear and thermally-stable lithium arylcuprates, [Cu(2)Li(2)Mes(4)] and [Cu(3)LiMes(4)], are reported and [Cu(3)LiMes(4)] is shown to be a highly active promoter for the 1,4-addition of organolithiums to enones.

引用

页码：304 / 306

页数：3

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