共 22 条
Kinetic resolution and asymmetric oxidation as combined routes to chiral sulfoxides
被引:43
作者:
Lattanzi, A
[1
]
Bonadies, F
[1
]
Senatore, A
[1
]
Soriente, A
[1
]
Scettri, A
[1
]
机构:
[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,I-00185 ROME,ITALY
关键词:
D O I:
10.1016/S0957-4166(97)00268-1
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Non-racemic sulfoxides are accessible through a modified Sharpless kinetic resolution of racemic sulfoxides. Furthermore, thanks to enantioconvergence of asymmetric oxidation and kinetic resolution a successful improvement of e.e. is achievable. (C) 1997 Elsevier Science Ltd.
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页码:2473 / 2478
页数:6
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