Conductance and stochastic switching of ligand-supported linear chains of metal atoms

被引：157

作者：

Chen, I-Wen Peter

Fu, Ming-Dung

Tseng, Wei-Hsiang

Yu, Jian-Yuan

Wu, Sung-Hsun

Ku, Chia-Jui

Chen, Chun-hsien ^{[1
]}

Peng, Shie-Ming

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[3] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 35期

关键词：

electron transport; metal-metal interactions; molecular electronics; scanning probe microscopy; single-molecule studies;

D O I：

10.1002/anie.200600800

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) An alternative string theory: The current-versus-potential behavior of metal atom strings (Ni, Co, Cr) is dependent on the strength of the d-orbital coupling along the metal atom chain. Penta- and heptachromium strings each exhibit two sets of primary I-V curves, which depend on whether the Cr-Cr bonds alternate and are localized, or are delocalized (see picture). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：5814 / 5818

页数：5

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