A Porous Coordination Polymer with Accessible Metal Sites and its Complementary Coordination Action

被引：48

作者：

Sakamoto, Hirotoshi ^{[1
]}

Matsuda, Ryotaro ^{[2
,3
]}

Bureekaew, Sareeya ^{[1
]}

Tanaka, Daisuke ^{[3
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ Katsura, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 20期

关键词：

adsorption; coordination polymers; copper; crystal engineering; microporous materials; POSTSYNTHETIC COVALENT MODIFICATION; ORGANIC FRAMEWORK; HYDROGEN STORAGE; ADSORPTION; SEPARATION; CATALYSIS; NETWORK; PYRAZINE-2,3-DICARBOXYLATE; FUNCTIONALIZATION; ADSORBENTS;

D O I：

10.1002/chem.200802730

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to demonstrate a Porous coordination polymer (PCP) in which the active metal sites were stabilized by labile coordination atoms in the framework. It was also demonstrated that the PCPs were able to realize guest-accessible metal sites without loss of the permanent porosity of the framework. It was confirmed from the sorption behavior that such an accessible metal site provided by the framework rearrangement system possessed affinity for specific guest molecules. A PCP was obtained as blue crystals by the reaction of [Cu-(ClO4)2]·6H2O with Na2pzdc and L in a H2O/THF medium. The crystal structure of 1·H2Ob·4H2Oc was determined by X-ray crystallography.

引用

页码：4985 / 4989

页数：5

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