One-pot electrocatalytic oxidation of glycerol to DHA

被引：118

作者：

Ciriminna, Rosaria

Palmisano, Giovanni

Della Pina, Cristina

Rossi, Michele

Pagliaro, Mario

机构：

[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, Italy

[2] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, I-90128 Palermo, Italy

[3] Univ Milan, Dipartimento Chim Inorgan, I-20133 Milan, Italy

[4] CNR, Inst Sci Eth & Methodol, I-90146 Palermo, Italy

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 39期

关键词：

D O I：

10.1016/j.tetlet.2006.07.123

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One-pot, waste-free oxidation of glycerol to 1,3-dihydroxyacetone (DHA) was achieved by simply applying a small electric potential (I. I V vs Ag/AgCl) to a glycerol solution in water buffered at pH 9.1 in the presence of 15 mol% TEMPO (2,2,6,6tetramethylpiperidine-l-oxyl). Prolonging the reaction time affords comparable amounts of hydroxypyruvic acid. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：6993 / 6995

页数：3

共 6 条

[1] Development of a transient segregated mathematical model of the semicontinuous microbial production process of dihydroxyacetone [J].