Kinetic and selectivity control of TEMPO electro-mediated oxidation of alcohols

被引：61

作者：

Liaigre, D

Breton, T

Beigsir, EM

机构：

[1] BioCydex, F-86022 Poitiers, France

[2] Univ Poitiers, Catalyse Chim Organ Lab, Equipe Electrocatalyse, CNRS,UMR 6503, F-86022 Poitiers, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2005年 / 7卷 / 03期

关键词：

electrosynthesis; oxidation; TEMPO; carbohydrates; alcohols;

D O I：

10.1016/j.elecom.2005.01.002

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

TEMPO electro-mediated oxidation of alcohols has been investigated in aqueous and hydro-organic media. Mono- and poly-saccharides, aryl alcohols and heterocyclic alcohols were converted into the corresponding carbonyls in good chemical and Faradaic yields. In both solvents, the electrochemically generated TEMPO+ was used in catalytic amount and the kinetics was found to be controlled by the diffusion step. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：312 / 316

页数：5

共 7 条

[1]

ANELLI PL, 1987, J ORG CHEM, V52, P2559

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