Both reduction of the intensity of aluminum-related photoluminescence after hydrogenation and the phenomenon of the optical quenching of the Al bound exciton (Al-BE) previously reported for hydrogenated 6H-SiC was observed now in the 4H-SiC polytype. Hydrogenation caused also a reduction of the nitrogen-aluminum donor-acceptor pair emission. Prolonged excitation of hydrogenated samples with above-band gap light resulted in additional quenching of the residual Al-BE photoluminescence. The quenching kinetics and some differences between the 6H and 4H polytypes are investigated. The observed phenomena are attributed to optically enhanced passivation of Al acceptors with hydrogen. (C) 2002 American Institute of Physics.