A remarkable ene-like reaction: Development and synthetic applications

被引：24

作者：

Ciufolini, MA

Deaton, MV

Zhu, SR

Chen, MY

机构：

来源：

TETRAHEDRON | 1997年 / 53卷 / 48期

关键词：

D O I：

10.1016/S0040-4020(97)01016-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic ene-like reaction of aldehydes with those vinyl ethers that display the oxygen functionality at the central carbon of an allylic system, e.g., 2-methoxypropene, is discussed in detail. The reaction is promoted by 0.05 eguiv. of the 1:1 complex of Yb(fod)(3) and acetic acid, and it is forms the centerpiece of our synthesis of chlorovulone II, mitomycinoids and phyllanthocin. (C) 1997 Elsevier Science Ltd.

引用

页码：16299 / 16312

页数：14

共 74 条

[71] STUDIES ON THE INTRAMOLECULAR COMPETITIVE ADDITION OF CARBON RADICALS TO ALDEHYDE AND ALKENYL GROUPS [J].