Unsymmetrical diaryl Sulfones through palladium-catalyzed coupling of aryl boronic acids and arylsulfonyl chlorides

被引：124

作者：

Bandgar, BP ^{[1
]}

Bettigeri, SV ^{[1
]}

Phopase, J ^{[1
]}

机构：

[1] Swami Ramanand Teerth Marathwada Univ, Sch Chem Sci, Organ Chem Res Lab, Vishnupuri 431606, Nanded, India

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 13期

关键词：

D O I：

10.1021/ol049692c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient method for the synthesis of unsymmetrical diaryl sulfones using the palladium-catalyzed coupling of aryl boronic acids and arylsulfonyl chlorides has been developed. High product yields, a short reaction time, and mild reaction conditions are important features of this method.

引用

页码：2105 / 2108

页数：4

共 38 条

[1] REACTIONS OF ORGANOLITHIUM COMPOUNDS WITH SULFONATE ESTERS - NOVEL SULFONE SYNTHESIS [J].

BAARSCHERS, WH .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (19) :3056-3059

[2]

Bandgar BP, 2002, SYNLETT, P735

[3] Synthesis of sulfones using sodium perchlorate as a catalyst under neutral conditions [J].

Bandgar, BP ;

Kamble, VT ;

Fulse, DB ;

Deshmukh, MV .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) :1105-1107

[4] Zinc-mediated fast sulfonylation of aromatics [J].

Bandgar, BP ;

Kasture, SP .

SYNTHETIC COMMUNICATIONS, 2001, 31 (07) :1065-1068

[5] An efficient copper catalyst for the formation of sulfones from sulfinic acid salts and aryl iodides [J].

Baskin, JM ;

Wang, ZY .

ORGANIC LETTERS, 2002, 4 (25) :4423-4425

[6]

Block E., 1980, CHEM FUNCTIONAL 1 SE

[7] Unsymmetrical diaryl sulfones through palladium-catalyzed coupling of aryl iodides and arenesulfinates [J].

Cacchi, S ;

Fabrizi, G ;

Goggiamani, A ;

Parisi, LM .

ORGANIC LETTERS, 2002, 4 (26) :4719-4721

[8] Lipophilicity behavior of model and medicinal compounds containing a sulfide, sulfoxide, or sulfone moiety [J].

Caron, G ;

Gaillard, P ;

Carrupt, PA ;

Testa, B .

HELVETICA CHIMICA ACTA, 1997, 80 (02) :449-462

[9] Fe(III) exchanged montmorillonite: A mild and eco-friendly catalyst for sulfonylation of aromatics [J].

Choudary, BM ;

Chowdari, NS ;

Kantam, ML ;

Kannan, R .

TETRAHEDRON LETTERS, 1999, 40 (14) :2859-2862

[10] Imidazole-containing diarylether and diarylsulfone inhibitors of farnesyl-protein transferase [J].

Dinsmore, CJ ;

Williams, TM ;

O'Neill, TJ ;

Liu, DM ;

Rands, E ;

Culberson, JC ;

Lobell, RB ;

Koblan, KS ;

Kohl, NE ;

Gibbs, JB ;

Oliff, AI ;

Graham, SL ;

Hartman, GD .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1999, 9 (23) :3301-3306

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