Equivalence between thermal and room temperature UV light-modulated responses of gas sensors based on individual SnO2 nanowires

被引:188
作者
Prades, J. D. [1 ]
Jimenez-Diaz, R. [1 ]
Hernandez-Ramirez, F. [2 ]
Barth, S. [3 ]
Cirera, A. [1 ]
Romano-Rodriguez, A. [1 ]
Mathur, S. [3 ,4 ]
Morante, J. R. [1 ]
机构
[1] Univ Barcelona, Dept Elect, EME XaRMAE IN2UB, Barcelona, Spain
[2] Elect Nanosyst SL, Barcelona, Spain
[3] Leibniz Inst New Mat, Saarbrucken, Germany
[4] Univ Cologne, Dept Inorgan Chem, Cologne, Germany
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2009年 / 140卷 / 02期
关键词
Monocrystalline; Metal oxide; SnO2; Nanowire; Photoactivation; Gas Sensor; TIN OXIDE; SENSING PROPERTIES; AB-INITIO; ACTIVATION; ADSORPTION; NO2; SURFACE; FILMS;
D O I
10.1016/j.snb.2009.04.070
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We demonstrate that illuminating metal oxide gas sensors with ultra-violet light is a viable alternative not only to activate but also to modulate their response towards oxidizing gases. Here, the performance of individual monocrystalline SnO2 nanowires to NO2 at room temperature as function of the flux and the energy of photons is studied. The results reveal that nearly identical responses, similar to thermally activated sensor surfaces, can be achieved by choosing the optimal illumination conditions. On the basis these results, a qualitative model to explain the response of these sensors towards oxidizing gases is proposed. This finding paves the way to the development of conductometric gas sensors operating at room temperature. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:337 / 341
页数:5
相关论文
共 36 条
[1]   Light enhanced NO2 gas sensing with tin oxide at room temperature:: conductance and work function measurements [J].
Anothainart, K ;
Burgmair, A ;
Karthigeyan, A ;
Zimmer, M ;
Eisele, I .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :580-584
[2]   Metal oxide-based gas sensor research: How to? [J].
Barsan, N. ;
Koziej, D. ;
Weimar, U. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 121 (01) :18-35
[3]   The surface and materials science of tin oxide [J].
Batzill, M ;
Diebold, U .
PROGRESS IN SURFACE SCIENCE, 2005, 79 (2-4) :47-154
[4]   Photosensitivity activation of SnO2 thin film gas sensors at room temperature [J].
Camagni, P ;
Faglia, G ;
Galinetto, P ;
Perego, C ;
Samoggia, G ;
Sberveglieri, G .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 31 (1-2) :99-103
[5]   SnO2 RGTO UV activation for CO monitoring [J].
Comini, E ;
Ottini, L ;
Faglia, G ;
Sberveglieri, G .
IEEE SENSORS JOURNAL, 2004, 4 (01) :17-20
[6]   UV light activation of tin oxide thin films for NO2 sensing at low temperatures [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 78 (1-3) :73-77
[7]   Light enhanced gas sensing properties of indium oxide and tin dioxide sensors [J].
Comini, E ;
Cristalli, A ;
Faglia, G ;
Sberveglieri, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 65 (1-3) :260-263
[8]   Highly sensitive room temperature sensors based on the UV-LED activation of zinc oxide nanoparticles [J].
Costello, B. P. J. de lacy ;
Ewen, R. J. ;
Ratcliffe, N. M. ;
Richards, M. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 134 (02) :945-952
[9]  
Desjonqueres M.C., 1996, Concepts in Surface Physics
[10]   Influence on the gas sensor performances of the metal chemical states introduced by impregnation of calcinated SnO2 sol-gel nanocrystals [J].
Diéguez, A ;
Vilà, A ;
Cabot, A ;
Romano-Rodríguez, A ;
Morante, JR ;
Kappler, J ;
Bârsan, N ;
Weimar, U ;
Göpel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 68 (1-3) :94-99