Synthesis of isoquinolines via visible light-promoted insertion of vinyl isocyanides with diaryliodonium salts

被引：110

作者：

Jiang, Heng ^{[1
]}

Cheng, Yuanzheng ^{[1
]}

Wang, Ruzhi ^{[1
]}

Zhang, Yan ^{[1
]}

Yu, Shouyun ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 46期

基金：

中国国家自然科学基金;

关键词：

PERIPHERAL BENZODIAZEPINE-RECEPTOR; MEDIATED ELECTROPHILIC CYCLIZATION; H BOND ACTIVATION; DE-NOVO SYNTHESIS; SUBSTITUTED ISOQUINOLINES; PHOTOREDOX CATALYSIS; PHENANTHRIDINE DERIVATIVES; INTERNAL ALKYNES; SULFONYLMETHYL ISOCYANIDES; REGIOSELECTIVE SYNTHESIS;

D O I：

10.1039/c4cc01122h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthetic strategy for multi-substituted isoquinoline derivatives has been developed using visible light-promoted vinyl isocyanide insertion with diaryliodonium salts at room temperature. The methodology presented here represents the first example of isoquinoline synthesis via somophilic isocyanide insertion.

引用

页码：6164 / 6167

页数：4

共 56 条

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