An IR- and EXAFS-study of the precursor system lead(II) acetate trihydrate, dissolved in methanol and 2-methoxyethanol

被引：12

作者：

Kolb, U ^{[1
]}

Gutwerk, D ^{[1
]}

Beudert, R ^{[1
]}

Bertagnolli, H ^{[1
]}

机构：

[1] UNIV STUTTGART, INST PHYS CHEM, D-70550 STUTTGART, GERMANY

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1997年 / 217卷 / 2-3期

关键词：

D O I：

10.1016/S0022-3093(97)00153-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The solid phase of lead(II) acetate trihydrate and a solution of this compound in methanol as a potential monodentate ligand and in 2-methoxyethanol as a potential bidendate ligand were investigated by IR- and EXAFS-spectroscopy. The structures of the lead compound in methanol and 2-methoxyethanol are identical or very similar. Lead(II) acetate trihydrate forms a subacetate in both solutions. 3Pb(OOCCH3)(2) . PbO . H2O can be isolated as precipitate in the methanolic solution at room temperature and, dissolved in 2-methoxyethanol, after refluxing the solution. (C) 1997 Elsevier Science B.V.

引用

页码：162 / 166

页数：5

共 15 条

[1] SOL-GEL-DERIVED PBTIO3 [J].

BLUM, JB ;

GURKOVICH, SR .

JOURNAL OF MATERIALS SCIENCE, 1985, 20 (12) :4479-4483

[2] C-13 CP MAS NMR AND CRYSTALLOGRAPHIC INVESTIGATIONS OF THE STRUCTURE AND SOLID-STATE TRANSFORMATIONS OF LEAD(II) ACETATE TRIHYDRATE [J].

BRYANT, RG ;

CHACKO, VP ;

ETTER, MC .

INORGANIC CHEMISTRY, 1984, 23 (22) :3580-3584

[3]

CALZADA ML, 1993, J MATER SCI LETT, V12, P1221

[4] XAFS SPECTROSCOPY OF LIQUID AND AMORPHOUS SYSTEMS - PRESENTATION AND VERIFICATION OF A NEWLY DEVELOPED PROGRAM PACKAGE [J].

ERTEL, TS ;

BERTAGNOLLI, H ;

HUCKMANN, S ;

KOLB, U ;

PETER, D .

APPLIED SPECTROSCOPY, 1992, 46 (04) :690-698

[5] EXAFS INVESTIGATIONS OF AIR AND MOISTURE SENSITIVE LIQUID COMPOUNDS - DEVELOPMENT OF AN APPROPRIATE SAMPLE HOLDER WITH VARIABLE SAMPLE THICKNESS AND TEMPERATURE CONTROL [J].

ERTEL, TS ;

BERTAGNOLLI, H .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1993, 73 (02) :199-202

[6] COLLOIDAL PROCESSING OF PBZR1-XTIXO3 THIN-FILMS [J].

FAURE, SP ;

BARBOUX, P ;

GAUCHER, P ;

LIVAGE, J .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (07) :713-717

[7] MICROSTRUCTURE CHARACTERIZATION OF SOL-GEL DERIVED PZT FILMS [J].

HIGUCHI, K ;

MIYAZAWA, K ;

SAKUMA, T ;

SUZUKI, K .

JOURNAL OF MATERIALS SCIENCE, 1994, 29 (02) :436-441

[8]

Holleman A.F., 1985, Lehrbuch Der Anorganischen Chemie

[9] MICROSTRUCTURAL DEVELOPMENT AND ELECTRICAL-PROPERTIES OF SOL-GEL PREPARED LEAD ZIRCONATE-TITANATE THIN-FILMS [J].

HSUEH, CC ;

MECARTNEY, ML .

JOURNAL OF MATERIALS RESEARCH, 1991, 6 (10) :2208-2217

[10]

LI S, 1988, CAN CERAM QUART, V57, P61

← 1 2 →