Silapericyclyne, (Ph2SiCC)6:: Spontaneous conformational resolution of boat- and chair-'exploded' cyclohexane

被引：20

作者：

Unno, M ^{[1
]}

Saito, T ^{[1
]}

Matsumoto, H ^{[1
]}

机构：

[1] Gunma Univ, Fac Engn, Dept Appl Chem, Kiryu, Gumma 3768515, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 11期

关键词：

D O I：

10.1246/cl.1999.1235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silapericyclyne, (Ph2SiC = C)(6) was found to undergo spontaneous conformational resolution into the chair and boat conformations by crystallization from THF-MeOH. In solution, these two isomers rapidly interconvert, and could not be separately detected even at low temperature by H-1 NMR.

引用

页码：1235 / 1236

页数：2

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