Hydrogen-bonded pseudopolyrotaxanes

被引:43
作者
Asakawa, M
Ashton, PR
Brown, GR
Hayes, W
Menzer, S
Stoddart, JF
White, AJP
Williams, DJ
机构
[1] UNIV BIRMINGHAM, SCH CHEM, BIRMINGHAM B15 2TT, W MIDLANDS, ENGLAND
[2] ZENECA PHARMACEUT, MACCLESFIELD SK10 4TG, CHESHIRE, ENGLAND
[3] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED, DEPT CHEM, CHEM CRYSTALLOG LAB, LONDON SW7 2AY, ENGLAND
关键词
D O I
10.1002/adma.19960080105
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
That supramolecular order on the nanometer scale in the crystalline state can be created by using both pi-pi stacking and hydrogen bonding interactions marks a significant development in the fields of crystal engineering and supramolecular chemistry. The design and construction of pseudorotaxane monomers (see figure) via self-assembly is described, which are then further assembled to form linear pseudopolyrotaxane columns.
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页码:37 / +
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