Synthesis and characterization of μ-Oxodiiron(III) complexes of porphycenes with electron-withdrawing substituents

被引：15

作者：

Baba, T ^{[1
]}

Shimakoshi, H ^{[1
]}

Aritome, I ^{[1
]}

Hisaeda, Y ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 07期

关键词：

D O I：

10.1246/cl.2004.906

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

mu-Oxodiiron(III) complexes of porphycenes with electron-withdrawing Br-substituents have been synthesized. The crystal structure of a tetrabrominated complex was elucidated by X-ray analysis. The Br-substituted effects for the electronic spectra and electrochemical properties have been reported.

引用

页码：906 / 907

页数：2

共 7 条

[1] Coordination chemistry of iron porphycenes in the presence of CO, CO2, and N-methylimidazole:: Electrochemical, ESR, and UV-vis study [J].

Bernard, C ;

Le Mest, Y ;

Gisselbrecht, JP .

INORGANIC CHEMISTRY, 1998, 37 (02) :181-190

[2] OCTABROMOTETRAPHENYLPORPHYRIN AND ITS METAL DERIVATIVES - ELECTRONIC-STRUCTURE AND ELECTROCHEMICAL PROPERTIES [J].

BHYRAPPA, P ;

KRISHNAN, V .

INORGANIC CHEMISTRY, 1991, 30 (02) :239-245

[3] MECHANISM OF CATALYTIC OXYGENATION OF ALKANES BY HALOGENATED IRON PORPHYRINS [J].

GRINSTAFF, MW ;

HILL, MG ;

LABINGER, JA ;

GRAY, HB .

SCIENCE, 1994, 264 (5163) :1311-1313

[4] Cobaltporphycenes as catalysts. The oxidation of vinyl ethers via the formation and dissociation of cobalt-carbon bonds [J].

Hayashi, T ;

Okazaki, K ;

Urakawa, N ;

Shimakoshi, H ;

Sessler, JL ;

Vogel, E ;

Hisaeda, Y .

ORGANOMETALLICS, 2001, 20 (14) :3074-3078

[5] MU-OXODIIRON(III) COMPLEXES OF PORPHYCENES [J].

LAUSMANN, M ;

ZIMMER, I ;

LEX, J ;

LUEKEN, H ;

WIEGHARDT, K ;

VOGEL, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07) :736-739

[6]

VOGEL E, 1986, ANGEW CHEM INT EDIT, V25, P2557

[7] ISOCORROLES - NOVEL TETRAPYRROLIC MACROCYCLES [J].

WILL, S ;

RAHBAR, A ;

SCHMICKLER, H ;

LEX, J ;

VOGEL, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12) :1390-1393

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