Using Soluble Polymer Supports To Facilitate Homogeneous Catalysis

被引：312

作者：

Bergbreiter, David E. ^{[1
]}

Tian, Jianhua ^{[1
]}

Hongfa, Chayanant ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMICAL REVIEWS | 2009年 / 109卷 / 02期

基金：

美国国家科学基金会;

关键词：

PHASE-TRANSFER LIGANDS; HYDROLYTIC KINETIC RESOLUTION; SUPERCRITICAL CARBON-DIOXIDE; CROSS-LINKED POLYSTYRENE; POLY(ETHYLENE GLYCOL)-SUPPORTED TEMPO; HIGHLY ENANTIOSELECTIVE EPOXIDATION; STABILIZED PALLADIUM NANOPARTICLES; FLUOROUS BIPHASE HYDROFORMYLATION; ASYMMETRIC TRANSFER HYDROGENATION; END-FUNCTIONALIZED POLYSTYRENES;

D O I：

10.1021/cr8004235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review of various research studies conducted since 2002 on the use of soluble polymer supports to facilitate homogeneous catalysis is presented. TEMPO is a commonly used organocatalyst for the selective oxidation of primary alcohols to aldehydes. Use of PEG-supported proline as a catalyst is described in enantioselective conjugate addition reactions. A phosphonium salt is described and is found to deliver catalyzed formation of cyclic carbonates, while intermediate cyclic carbonates could be used without isolation as a phosgene-equivalent. The synthesis of three types of PEG-supported salen ligands could be used to catalyze the addition of diethyl zinc to aldehydes. A study including the use of PEG supports to prepare a tartate ester library is an effort to probe the effect of tartrate structure on stereoselectivity in Sharpless asymmetric epoxidation of allylic alcohols.

引用

页码：530 / 582

页数：53

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