Role of defects in the anomalous photoconductivity in ZnO nanowires

被引:146
作者
Bera, A. [1 ]
Basak, D. [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, India
关键词
adsorption; annealing; defect states; electron-hole recombination; energy gap; II-VI semiconductors; nanotechnology; nanowires; oxygen; photoconductivity; photoluminescence; semiconductor growth; semiconductor quantum wires; water; wide band gap semiconductors; zinc compounds; NANORODS;
D O I
10.1063/1.3123167
中图分类号
O59 [应用物理学];
学科分类号
摘要
The anomalous photocurrent decay in aqueous solution grown ZnO nanowires (NWs) under steady ultraviolet light illumination have been investigated. The photocurrent growth-decay measurements using the above-band and subband gap light excitation energies in the as-grown and annealed NWs show that while a V-Zn-related defect complex is formed by the surface adsorbed H2O molecules, a faster carrier trapping by the surface adsorbed O-2 molecules and a slower carrier recombination at the defect, Zn-i cause the photocurrent decay under steady illumination supported by the results of the photocurrent spectra and photoluminescence measurements. The predicted mechanism has been explained through a model.
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页数:3
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