On the distinction between radical chemistry and gif chemistry

被引：17

作者：

Barton, DHR

Launay, F

LeGloahec, VN

Li, TS

Smith, F

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(97)10308-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Normalized data for cyclooctane and for cyclododecane are compared with cyclohexane as unity. In radical chemistry cyclooctane is 2-3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexane is more reactive than cyclooctane or cyclododecane. Thus by simple competitive experiments a distinction between radical chemistry and Gif chemistry can be made. (C) 1997 Elsevier Science Ltd.

引用

页码：8491 / 8494

页数：4

共 19 条

[1] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .24. THE USE OF TERT-BUTYL HYDROPEROXIDE - GOAGG(IV) AND GOAGG(V)
BARTON, DHR
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[J]. TETRAHEDRON, 1994, 50 (01) : 19 - 30
[2] Models for non-heme oxidation enzymes
Barton, DHR
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[3] The selective functionalization of saturated hydrocarbons .32. Distinction between the Fe-II-Fe-IV and Fe-III-Fe-V manifolds in Gif chemistry. The importance of carboxylic acids for alkane activation. Evidence for a dimeric iron species involved in Gif-type chemistry
Barton, DHR
Hu, B
Taylor, DK
Wahl, RUR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (06): : 1031 - 1041
[4] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .26. IONIC SUBSTITUTION-REACTIONS IN GOAGG(IV) CHEMISTRY - THE CONSTRUCTION OF C-N, C-S AND C-C BONDS
BARTON, DHR
CHAVASIRI, W
[J]. TETRAHEDRON, 1994, 50 (01) : 47 - 60
[5] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .23. GIF-TYPE BROMINATION AND CHLORINATION OF SATURATED-HYDROCARBONS - A NONRADICAL REACTION
BARTON, DHR
CSUHAI, E
DOLLER, D
[J]. TETRAHEDRON, 1992, 48 (42) : 9195 - 9206
[6] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .25. IONIC SUBSTITUTION-REACTIONS IN GOAGG(IV) CHEMISTRY - THE FORMATION OF CARBON-HALOGEN BONDS
BARTON, DHR
BEVIERE, SD
CHAVASIRI, W
[J]. TETRAHEDRON, 1994, 50 (01) : 31 - 46
[7] The functionalization of saturated hydrocarbons .39. Further evidence for the role of the iron-carbon bond in Gif chemistry
Barton, DHR
Salgueiro, MC
MacKinnon, J
[J]. TETRAHEDRON, 1997, 53 (22) : 7417 - 7428
[8] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY
BARTON, DHR
DOLLER, D
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (11) : 504 - 512
[9] BARTON DHR, UNPUB NEW J CHEM
[10] BARTON DHR, 1997, J CHEM SOC CHEM COMM, P557

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