On the distinction between radical chemistry and gif chemistry

被引:17
作者
Barton, DHR
Launay, F
LeGloahec, VN
Li, TS
Smith, F
机构
[1] Department of Chemistry, Texas A and M University, College Station
关键词
D O I
10.1016/S0040-4039(97)10308-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Normalized data for cyclooctane and for cyclododecane are compared with cyclohexane as unity. In radical chemistry cyclooctane is 2-3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexane is more reactive than cyclooctane or cyclododecane. Thus by simple competitive experiments a distinction between radical chemistry and Gif chemistry can be made. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:8491 / 8494
页数:4
相关论文
共 19 条