Crystal engineering in ionic liquids.: The crystal structures of [Mppyr]3[Ndl6] and [Bmpyr]4[Ndl6][Tf2N]

被引：41

作者：

Babai, Arash ^{[1
]}

Mudring, Anja-Verena ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 13期

关键词：

D O I：

10.1021/ic060414e

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Single crystals of [mppyr][NdI6] and [bmpyr][NdI6][Tf2N] are the first surprising examples of how the cation of an ionic liquid determines the compound formation from an ionic liquid. Depending upon the variation of the length of the alkyl chain of the quaternary pyrrolidinium cation (C3 and C4, respectively), incorporation of the anion of the ionic liquid, [Tf2N](-), can either be evoked or suppressed.

引用

页码：4874 / 4876

页数：3

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