Proton migration on the [60]fullerene cage of 1-tert-butyl-1,4-dihydro[60]fullerene to yield the 1,2-isomer

被引：12

作者：

Banim, F

Cardin, DJ

Heath, P

机构：

[1] Department of Chemistry, University of Reading, Reading Berkshire, RG6 6AD, Whiteknights

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a605859k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton NMR data on the base catalysed rearrangement of 1-tert-butyl-1,4-dihydro[60]fullerene to the 1,2-isomer reveal a second order reaction and an activation energy of 56.1 kJ mol(-1).

引用

页码：25 / 26

页数：2

共 6 条

[1] CHOHO K, UNPUB
[2] SYNTHESIS, CHEMISTRY, AND PROPERTIES OF A MONOALKYLATED BUCKMINSTERFULLERENE DERIVATIVE, T-BUC-60 ANION
FAGAN, PJ
KRUSIC, PJ
EVANS, DH
LERKE, SA
JOHNSTON, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) : 9697 - 9699
[3] TITRATION OF C-60 - A METHOD FOR THE SYNTHESIS OF ORGANOFULLERENES
HIRSCH, A
SOI, A
KARFUNKEL, HR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (06): : 766 - 768
[4] HIRSCH A, 1992, ANGEW CHEM, V104, P808
[5] REGIOSPECIFIC COORDINATION OF TERT-BUTYLFULLERIDE ION AND 1,4-DICYCLOPROPYLTROPYLIUM ION - SYNTHESIS OF A DIALKYLDIHYDROFULLERENE HAVING A HETEROLYTICALLY DISSOCIATIVE CARBON-CARBON SIGMA-BOND
KITAGAWA, T
TANAKA, T
TAKATA, Y
TAKEUCHI, K
KOMATSU, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (06) : 1490 - 1491
[6] SEMIEMPIRICAL CALCULATIONS OF DIHYDROGENATED BUCKMINSTERFULLERENES, C60H2
MATSUZAWA, N
DIXON, DA
FUKUNAGA, T
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (19) : 7594 - 7604

← 1 →