Guest-induced formation of an icosahedral coordination cage

被引:46
作者
Brasey, Thomas [1 ]
Scopelliti, Rosario [1 ]
Severin, Kay [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, Lausanne, Switzerland
关键词
D O I
10.1039/b607512f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A coordination cage with an elusive icosahedral geometry was obtained by K+-induced rearrangement of a hexanuclear [(cymene) Ru(pyridine-3,5-dicarboxylate)](6) complex.
引用
收藏
页码:3308 / 3310
页数:3
相关论文
共 56 条
[1]   A very large metallosupramolecular capsule with cube-like 43 topology assembled from twelve Cu(II) centers and eight tri-bidentate tri-anionic ligands derived from 2,4,6-triphenylazo-1,3,5-trihydroxybenzene [J].
Abrahams, BF ;
Egan, SJ ;
Robson, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3535-3536
[2]   Selecting different complexes from a dynamic combinatorial library of coordination compounds [J].
Albrecht, M ;
Janser, I ;
Runsink, J ;
Raabe, G ;
Weis, P ;
Fröhlich, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (48) :6662-6666
[3]   (η5-pentamethylcyclopentadienyl)rhodium and -iridium complexes with weakly and strongly coordinating anions:: Isolation and first X-ray molecular structures of the tris(solvent) complexes [(C5Me5)M(acetone)2(H2O)][BF4]2 (M = Rh, Ir) [J].
Amouri, H ;
Guyard-Duhayon, C ;
Vaissermann, J ;
Rager, MN .
INORGANIC CHEMISTRY, 2002, 41 (06) :1397-1403
[4]  
Amouri H, 2001, ANGEW CHEM INT EDIT, V40, P3636, DOI 10.1002/1521-3773(20011001)40:19<3636::AID-ANIE3636>3.0.CO
[5]  
2-I
[6]   Three-dimensional supermolecules assembled from a tris(Zn2+-cyclen) complex and di- and trianionic cyanuric acid in aqueous solution (cyclen=1,4,7,10-tetraazacyclododecane) [J].
Aoki, S ;
Shiro, M ;
Koike, T ;
Kimura, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (04) :576-584
[7]  
Aoki S, 2002, CHEM-EUR J, V8, P929, DOI 10.1002/1521-3765(20020215)8:4<929::AID-CHEM929>3.0.CO
[8]  
2-Q
[9]  
Bell ZR, 2002, ANGEW CHEM INT EDIT, V41, P2515, DOI 10.1002/1521-3773(20020715)41:14<2515::AID-ANIE2515>3.0.CO
[10]  
2-Q