学术探索
学术期刊
新闻热点
数据分析
智能评审

Selecting different complexes from a dynamic combinatorial library of coordination compounds

被引：66
作者：
Albrecht, M
Janser, I
Runsink, J
Raabe, G
Weis, P
Fröhlich, R
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 48期
关键词：
D O I：
10.1002/anie.200453975
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A choice selection: A dynamic combinatorial library of oligonuclear coordination compounds is formed from a flexible tris(catechol) ligand with titanium(iv) ions in the presence of lithium carbonate or potassium carbonate. A trinuclear complex (1) can be isolated by crystallization from DMF. In contrast, well-defined mononuclear (2) compounds are obtained by addition of Na+ as a template, and tetranuclear compounds (3) are isolated by changing the solvent to DMSO.
引用
收藏
页码：6662 / 6666
页数：5
相关论文
共 71 条
  • [1] PREPARATION, PROPERTIES AND COORDINATION BEHAVIOR OF PLANAR OR TRIDIMENSIONAL COMPARTMENTAL SCHIFF-BASES
    AGUIARI, A
    BULLITA, E
    CASELLATO, U
    GUERRIERO, P
    TAMBURINI, S
    VIGATO, PA
    RUSSO, U
    [J]. INORGANICA CHIMICA ACTA, 1994, 219 (1-2) : 135 - 146
  • [2] MACROCYCLIC AND MACROACYCLIC COMPARTMENTAL SCHIFF-BASES - SYNTHESIS, CHARACTERIZATION, X-RAY STRUCTURE AND INTERACTION WITH METAL-IONS
    AGUIARI, A
    BULLITA, E
    CASELLATO, U
    GUERRIERO, P
    TAMBURINI, S
    VIGATO, PA
    [J]. INORGANICA CHIMICA ACTA, 1992, 202 (02) : 157 - 171
  • [3] Dicatechol-diimines:: easily accessible ligands for the self-assembly of dinuclear triple-stranded helicates
    Albrecht, M
    Janser, I
    Kamptmann, S
    Weis, P
    Wibbeling, B
    Fröhlich, R
    [J]. DALTON TRANSACTIONS, 2004, (01) : 37 - 43
  • [4] A metallosupramolecular tetrahedron with a huge internal cavity
    Albrecht, M
    Janser, I
    Meyer, S
    Weis, P
    Fröhlich, R
    [J]. CHEMICAL COMMUNICATIONS, 2003, (23) : 2854 - 2855
  • [5] 3,3′-{(1E,2E)-hydrazine-1,2-diylidenedi[(E)methylylidene]}dibenzene-1,2-diol (BCAz-H4):: an easy to prepare but very useful building block for the self-assembly of triple-stranded helicates;: the X-ray crystal structure of Na4[(BCAz)3Ti2]•7 dmf•H2O
    Albrecht, M
    Kamptmann, S
    Fröhlich, R
    [J]. POLYHEDRON, 2003, 22 (05) : 643 - 647
  • [6] Size-selectivity in the template-directed assembly of dinuclear triple-stranded helicates
    Albrecht, M
    Blau, O
    Fröhlich, R
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) : 4867 - 4872
  • [7] Solubilization of a self-assembled metallocryptand by addition of K+
    Albrecht, M
    Blau, O
    [J]. CHEMICAL COMMUNICATIONS, 1997, (04) : 345 - 346
  • [8] Albrecht M, 1999, ANGEW CHEM INT EDIT, V38, P3463, DOI 10.1002/(SICI)1521-3773(19991203)38:23<3463::AID-ANIE3463>3.0.CO
  • [9] 2-E
  • [10] Albrecht M, 1999, CHEM-EUR J, V5, P48, DOI 10.1002/(SICI)1521-3765(19990104)5:1<48::AID-CHEM48>3.3.CO
12345678