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Selecting different complexes from a dynamic combinatorial library of coordination compounds

被引：66
作者：
Albrecht, M
Janser, I
Runsink, J
Raabe, G
Weis, P
Fröhlich, R
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 48期
关键词：
D O I：
10.1002/anie.200453975
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A choice selection: A dynamic combinatorial library of oligonuclear coordination compounds is formed from a flexible tris(catechol) ligand with titanium(iv) ions in the presence of lithium carbonate or potassium carbonate. A trinuclear complex (1) can be isolated by crystallization from DMF. In contrast, well-defined mononuclear (2) compounds are obtained by addition of Na+ as a template, and tetranuclear compounds (3) are isolated by changing the solvent to DMSO.
引用
收藏
页码：6662 / 6666
页数：5
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