Selective oxidation of tetralin over a chromium terephthalate metal organic framework, MIL-101

被引:124
作者
Kim, Jun [1 ]
Bhattacharjee, Samiran [1 ]
Jeong, Kwang-Eun [2 ]
Jeong, Soon-Yong [2 ]
Ahn, Wha-Seung [1 ]
机构
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
[2] KRICT, Appl Chem & Engn Div, Yuseong 305600, South Korea
关键词
CATALYTIC-PROPERTIES; LIQUID-PHASE; HYDROGEN STORAGE; STABILITY; MOFS;
D O I
10.1039/b902699a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MIL-101, a mesoporous chromium terephthalate metal organic framework, was found to be an efficient heterogeneous catalyst for selective oxidation of tetralin to 1-tetralone using tert-butyl hydroperoxide or acylperoxy radicals generated in situ from trimethylacetaldehyde and O-2 as an oxidant.
引用
收藏
页码:3904 / 3906
页数:3
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