Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores

被引:1302
作者
Horcajada, Patricia
Surble, Suzy
Serre, Christian
Hong, Do-Young
Seo, You-Kyong
Chang, Jong-San
Greneche, Jean-Marc
Margiolaki, Irene
Ferey, Gerard
机构
[1] Univ Versailles St Quentin Yvelines, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France
[2] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305600, South Korea
[3] Univ Maine, Lab Phys Etat Condense, CNRS, UMR 6087, F-72085 Le Mans 9, France
[4] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
D O I
10.1039/b704325b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).
引用
收藏
页码:2820 / 2822
页数:3
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