Preparation of graphene dispersions and graphene-polymer composites in organic media

被引:281
作者
Villar-Rodil, Silvia [1 ]
Paredes, Juan. I. [1 ]
Martinez-Alonso, Amelia [1 ]
Tascon, Juan. M. D. [1 ]
机构
[1] CSIC, Inst Nacl Carbon, E-33080 Oviedo, Spain
关键词
EXFOLIATED GRAPHITE OXIDE; FUNCTIONALIZED GRAPHENE; CARBON; ROUTE; REDUCTION;
D O I
10.1039/b904935e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene nanosheets in the form of chemically reduced graphene oxide have been prepared in organic media without the need to chemically functionalise the starting graphene oxide nanosheets. The preparation procedure is simple and similar to that previously used for the production of stable aqueous dispersions of graphene nanosheets. The resulting organic dispersions are homogeneous, exhibit long-term stability and are made up of graphene sheets a few hundred nanometres large. The ability to prepare graphene dispersions in organic media facilitates their combination with polymers, such as polyacrylonitrile and poly( methyl methacrylate), to yield homogeneous composites.
引用
收藏
页码:3591 / 3593
页数:3
相关论文
共 36 条
[1]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[2]   Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].
Berger, C ;
Song, ZM ;
Li, TB ;
Li, XB ;
Ogbazghi, AY ;
Feng, R ;
Dai, ZT ;
Marchenkov, AN ;
Conrad, EH ;
First, PN ;
de Heer, WA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916
[3]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[4]   Highly conductive carbon-nanotube/graphite-oxide hybrid films [J].
Cai, Dongyu ;
Song, Mo ;
Xu, Chenxi .
ADVANCED MATERIALS, 2008, 20 (09) :1706-+
[5]   Preparation of fully exfoliated graphite oxide nanoplatelets in organic solvents [J].
Cai, Dongyu ;
Song, Mo .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (35) :3678-3680
[6]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[7]   Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].
Fan, Xiaobin ;
Peng, Wenchao ;
Li, Yang ;
Li, Xianyu ;
Wang, Shulan ;
Zhang, Guoliang ;
Zhang, Fengbao .
ADVANCED MATERIALS, 2008, 20 (23) :4490-4493
[8]   Characterization of active sites on carbon catalysts [J].
Figueiredo, Jose L. ;
Pereira, Manuel F. R. ;
Freitas, Maria M. A. ;
Orfao, Jose J. M. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (12) :4110-4115
[9]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[10]   Electronic transport properties of individual chemically reduced graphene oxide sheets [J].
Gomez-Navarro, Cristina ;
Weitz, R. Thomas ;
Bittner, Alexander M. ;
Scolari, Matteo ;
Mews, Alf ;
Burghard, Marko ;
Kern, Klaus .
NANO LETTERS, 2007, 7 (11) :3499-3503