Catalytic Hydroaminoalkylation

被引：150

作者：

Roesky, Peter W. ^{[1
]}

机构：

[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 27期

关键词：

amines; homogeneous catalysis; tantalum; titanium; zirconium; H BOND ACTIVATION; ASYMMETRIC HYDROAMINATION; UNACTIVATED OLEFINS; ALKENES; REACTIVITY; COMPLEXES; NITROGEN; AMINES; ALPHA;

D O I：

10.1002/anie.200900735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Excellent couplings: Recent developments in the metal-catalyzed C - H activation of sp3 centers in an α position relative to an amine nitrogen atom are presented. Their reaction with alkenes to give alkylamines (hydroaminoalkylation) is also summarized (see general scheme). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4892 / 4894

页数：3

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