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Platinum-catalyzed intermolecular hydroamination of alkenes: Halide-anion-promoted catalysis

被引：95
作者：
Brunet, Jean-Jacques
Chu, Ngoc-Chau
Rodriguez-Zubiri, Mireia
机构：
[1] Univ Toulouse 3, CNRS, U8241, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] Inst Natl Polytech Toulouse, F-31077 Toulouse, France
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 30期
关键词：
alkenes; homogeneous catalysis; intermolecular hydroamination; ionic liquids; platinum;
D O I：
10.1002/ejic.200700737
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetraalkylphosphonium halides play the role of "promoters" for the previously unknown Pt-II-catalyzed hydroamination of alkenes. The promoting effect of these "cocatalysts" depends only upon their anionic moiety. The Pt-II/nBu(4)PBr system exhibits an unprecedented catalytic activity (aerobic conditions) for the hydroamination of ethylene and 1-hexene (regioselectivity > 95 %, Markovnikov).
引用
收藏
页码：4711 / 4722
页数：12
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