学术探索
学术期刊
新闻热点
数据分析
智能评审

Platinum-catalyzed intermolecular hydroamination of alkenes: Halide-anion-promoted catalysis

被引：95
作者：
Brunet, Jean-Jacques
Chu, Ngoc-Chau
Rodriguez-Zubiri, Mireia
机构：
[1] Univ Toulouse 3, CNRS, U8241, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] Inst Natl Polytech Toulouse, F-31077 Toulouse, France
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 30期
关键词：
alkenes; homogeneous catalysis; intermolecular hydroamination; ionic liquids; platinum;
D O I：
10.1002/ejic.200700737
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetraalkylphosphonium halides play the role of "promoters" for the previously unknown Pt-II-catalyzed hydroamination of alkenes. The promoting effect of these "cocatalysts" depends only upon their anionic moiety. The Pt-II/nBu(4)PBr system exhibits an unprecedented catalytic activity (aerobic conditions) for the hydroamination of ethylene and 1-hexene (regioselectivity > 95 %, Markovnikov).
引用
收藏
页码：4711 / 4722
页数：12
相关论文
共 125 条
  • [71] LAWRENCE SA, 2004, AMINES
  • [72] Phosphine gold(I)-catalyzed hydroamination of alkenes under thermal and microwave-assisted conditions
    Liu, Xin-Yuan
    Li, Cheng-Hui
    Che, Chi-Ming
    [J]. ORGANIC LETTERS, 2006, 8 (13) : 2707 - 2710
  • [73] Maitlis PM, 2004, DALTON T, P3409, DOI 10.1039/b410128f
  • [74] March J., 1992, ADV ORG CHEM
  • [75] PtCl2- and PtCl4-catalyzed cycloisomerization of polyunsaturated precursors
    Marco-Contelles, Jose
    Arroyo, Nieves
    Anjum, Shazia
    Mainetti, Emily
    Marion, Nicolas
    Cariou, Kevin
    Lemiere, Gilles
    Mouries, Virginie
    Fensterbank, Louis
    Malacria, Max
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (20) : 4618 - 4633
  • [76] Neutral Ti catalysts for the intramolecular hydroamination of alkenes
    Mueller, Carsten
    Loos, Christian
    Schulenberg, Nikola
    Doye, Sven
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (11) : 2499 - 2503
  • [77] Muller T. E., 1998, TRANSITION METALS OR, V2, P316
  • [78] Metal-initiated amination of alkenes and alkynes
    Muller, TE
    Beller, M
    [J]. CHEMICAL REVIEWS, 1998, 98 (02) : 675 - 703
  • [79] SYNTHETIC ASPECTS OF METAL-CATALYZED OXIDATIONS OF AMINES AND RELATED REACTIONS
    MURAHASHI, SI
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (22): : 2443 - 2465
  • [80] CATALYTIC ALKYL GROUP EXCHANGE-REACTION OF PRIMARY AND SECONDARY-AMINES
    MURAHASHI, SI
    YOSHIMURA, N
    TSUMIYAMA, T
    KOJIMA, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (15) : 5002 - 5011
3456789101112