Redox-active polypyrrole: Toward polymer-based batteries

被引：190

作者：

Song, Hyun-Kon

Palmore, G. Tayhas R. ^{[1
]}

机构：

[1] Brown Univ, Div Engn, Providence, RI 02912 USA

[2] Brown Univ, Dept Mol Pharmacol Physiol & Biotechnol, Providence, RI 02912 USA

来源：

ADVANCED MATERIALS | 2006年 / 18卷 / 13期

关键词：

D O I：

10.1002/adma.200600375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An energy-storage device consisting of polypyrrole (pPy) doped with indigo carmine (IC) and 2,2'-azinobis (3-ethylbenzothiazoline-6-sulfonate) (ABTS) has been fabricated. These redox-active conducting polymers (see figure) form the basis of a battery that depends on the faradaic reactions of the redox-active dopants, and performs better than conventional batteries and ultracapacitors at high power density.

引用

收藏

页码：1764 / +

页数：6

相关论文

共 14 条

[1]

[Anonymous], ADV POLYM SCI

[2] Polymer-based redox supercapacitors: A comparative study [J].

Arbizzani, C ;

Mastragostino, M ;

Meneghello, L .

ELECTROCHIMICA ACTA, 1996, 41 (01) :21-26

[3]

BARD AJ, 1980, ELECTROCHEMICAL METH

[4]

Conway B. E., 1999, ELECTROCHEMICAL SUPE, DOI DOI 10.1007/978-1-4757-3058-6

[5] Enhanced rate of the redox reaction of indigodisulfonate at electrodes coated with poly[1-methyl-3-(pyrrol-1-ylmethyl)pyridiniun]chloride films [J].

Komura, T ;

Kobayasi, T ;

Yamaguti, T ;

Takahasi, K .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 454 (1-2) :145-153

[6]

Linden D., 2001, Handbook of Batteries

[7] ELECTRICALLY CONDUCTIVE POLYMERS AS RECHARGEABLE BATTERY ELECTRODES [J].

NAEGELE, D ;

BITTIHN, R .

SOLID STATE IONICS, 1988, 28 :983-989

[8] THEORY AND APPLICATION OF CYCLIC VOLTAMMETRY FOR MEASUREMENT OF ELECTRODE REACTION KINETICS [J].

NICHOLSON, RS .

ANALYTICAL CHEMISTRY, 1965, 37 (11) :1351-+

[9] Electrochemically active polymers for rechargeable batteries [J].

Novak, P ;

Muller, K ;

Santhanam, KSV ;

Haas, O .

CHEMICAL REVIEWS, 1997, 97 (01) :207-281

[10] pH-Dependent rectification in redox polymers: Characterization of electrode-confined siloxane polymers containing naphthoquinone and benzylviologen subunits [J].

Palmore, GTR ;

Smith, DK ;

Wrighton, MS .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14) :2437-2450