Reciprocity Between Electroluminescence and Quantum Efficiency Used for the Characterization of Silicon Solar Cells

被引:78
作者
Kirchartz, Thomas [1 ]
Helbig, Anke [2 ]
Reetz, Wilfried [1 ]
Reuter, Michael [2 ]
Werner, Juergen H. [2 ]
Rau, Uwe [1 ]
机构
[1] Forschungszentrum Julich, Photovolta IEF5, D-52425 Julich, Germany
[2] Univ Stuttgart, Inst Phys Elekt, D-70569 Stuttgart, Germany
来源
PROGRESS IN PHOTOVOLTAICS | 2009年 / 17卷 / 06期
关键词
luminescence; reciprocity; LED; quantum efficiency; LIGHT;
D O I
10.1002/pip.895
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Spectrally and spatially resolved electroluminescence emission of crystalline silicon solar cells is interpreted in terms of two electro-optical reciprocity relations. The first relation links the photovoltaic quantum efficiency to the electroluminescence spectrum. Both methods contain information on recombination and the optical pathlength of the incident light, simultaneously. From the electroluminescence spectrum, we derive the pathlength enhancement factor of textured and untextured crystalline silicon solar cells. Further, we use local quantum efficiency measurements to quantitatively explain light induced current as well as panchromatic electroluminescence images. A second reciprocity relation connects open circuit voltage of a solar cell with the light emitting diode quantum efficiency of the same device. For a given quality of light trapping and a given open circuit voltage, we predict the attainable LED quantum efficiency and verify our results experimentally. Copyright (C) 2009 John Wiley & Sons, Ltd.
引用
收藏
页码:394 / 402
页数:9
相关论文
共 20 条
[1]   COUPLING OF LIGHT INTO MECHANICALLY TEXTURED SILICON SOLAR-CELLS - A RAY-TRACING STUDY [J].
BRENDEL, R .
PROGRESS IN PHOTOVOLTAICS, 1995, 3 (01) :25-38
[2]   A RECIPROCITY THEOREM FOR CHARGE COLLECTION [J].
DONOLATO, C .
APPLIED PHYSICS LETTERS, 1985, 46 (03) :270-272
[3]   Photographic surveying of minority carrier diffusion length in polycrystalline silicon solar cells by electroluminescence [J].
Fuyuki, T ;
Kondo, H ;
Yamazaki, T ;
Takahashi, Y ;
Uraoka, Y .
APPLIED PHYSICS LETTERS, 2005, 86 (26) :1-3
[4]   Efficient silicon light-emitting diodes [J].
Green, MA ;
Zhao, JH ;
Wang, AH ;
Reece, PJ ;
Gal, M .
NATURE, 2001, 412 (6849) :805-808
[5]  
GREEN MA, 1986, SOLAR CELLS OPERATIN, P92
[6]   Series resistance imaging of solar cells by voltage dependent electroluminescence [J].
Hinken, David ;
Ramspeck, Klaus ;
Bothe, Karsten ;
Fischer, Bernhard ;
Brendel, Rolf .
APPLIED PHYSICS LETTERS, 2007, 91 (18)
[7]   General parameterization of Auger recombination in crystalline silicon [J].
Kerr, MJ ;
Cuevas, A .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (04) :2473-2480
[8]   Comparative study of electroluminescence from Cu(In,Ga)Se2 and Si solar cells [J].
Kirchartz, T. ;
Rau, U. ;
Kurth, M. ;
Mattheis, J. ;
Werner, J. H. .
THIN SOLID FILMS, 2007, 515 (15) :6238-6242
[9]  
KIRCHARTZ T, 2008, MAT RES SOC S P SAN
[10]   Note on the interpretation of electroluminescence images using their spectral information [J].
Kirchartz, Thomas ;
Helbig, Anke ;
Rau, Uwe .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (12) :1621-1627