Polymer electrolytes for lithium ion batteries: a critical study

被引:375
作者
Arya, Anil [1 ]
Sharma, A. L. [1 ]
机构
[1] Cent Univ Punjab, Ctr Phys Sci, Bathinda 151001, Punjab, India
关键词
Polymer electrolytes; Lithium ion battery; Tem; FTIR; Electrochemical analysis; Transport mechanism; COMPOSITE POLYMER; MECHANICAL-PROPERTIES; ELECTROCHEMICAL PROPERTIES; CONDUCTIVITY ENHANCEMENT; POLY(ETHYLENE OXIDE); TRANSPORT-PROPERTIES; CERAMIC FILLER; PVC/PMMA BLEND; ELECTRICAL-PROPERTIES; THERMAL-PROPERTIES;
D O I
10.1007/s11581-016-1908-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polymer electrolytes (PEs) are an essential component being used in most energy storage/conversion devices. The present review article on a brief history, advantage, and their brief application of polymer electrolyte systems. It consists of a glimpse on liquid, gel, and solid polymer electrolyte and a contrast comparison concerning benefits/disadvantages among the three. The article started with a brief introduction of polymer electrolytes followed by their varieties and extreme uses. The role of host polymer matrix by taking numerous examples of polymer electrolyte published by the different renowned group of the concerned field has been explored. The criteria for selection of appropriate host polymer, salt, inorganic filler/clay, and aprotic solvents to be used in polymer electrolyte have been discussed in detail. The mostly used polymer, salt, solvents, and inorganic filler/clay list has been prepared in order to keep the data bank at one place for new researchers. This article comprises different methodologies for the preparation of polymer electrolyte films. The different self-proposed mechanisms (like VTF, WLF, free volume theory, dispersed/intercalated mechanisms, etc.) have been discussed in order to explain the lithium ion conduction in polymer electrolyte systems. A numerous characterization techniques and their resulting analysis have been summarized from the different published reports at one place for better awareness of the scientific community/reader of the area.
引用
收藏
页码:497 / 540
页数:44
相关论文
共 219 条
[81]   Studies of some poly(vinylidene fluoride) electrolytes [J].
Jiang, Z ;
Carroll, B ;
Abraham, KM .
ELECTROCHIMICA ACTA, 1997, 42 (17) :2667-2677
[82]   Polyvinyl Alcohol Based Solid Electrolyte Film: Synthesis, Characterization and Electrical Properties [J].
Karthik, Sekar ;
Suresh, Jayaseelan ;
Vakees, Ekambaram ;
Kayalvizhi, Muthu ;
Thangaraj, Venkatesan ;
Balaji, Kanagasabai ;
Selvasekarapandian, S. ;
Arun, Araichimani .
MACROMOLECULAR SYMPOSIA, 2016, 362 (01) :18-25
[83]  
Karuppasamy K, 2014, MAT SCI FORUM, V807
[84]   POLY(ETHYLENE OXIDE) ELECTROLYTES FOR OPERATION AT NEAR ROOM-TEMPERATURE [J].
KELLY, IE ;
OWEN, JR ;
STEELE, BCH .
JOURNAL OF POWER SOURCES, 1985, 14 (1-3) :13-21
[85]   Spectroscopic and electrochemical studies of PMMA-based gel polymer electrolytes modified with interpenetrating networks [J].
Kim, CS ;
Oh, SM .
JOURNAL OF POWER SOURCES, 2002, 109 (01) :98-104
[86]   Electrochemical characterization of poly (ethylene-co-methyl acrylate)-based gel polymer electrolytes for lithium-ion polymer batteries [J].
Kim, DW .
JOURNAL OF POWER SOURCES, 2000, 87 (1-2) :78-83
[87]   Solvent-free, PYR1A TFSI ionic liquid-based ternary polymer electrolyte systems I.: Electrochemical characterization [J].
Kim, Guk-Tae ;
Appetecchi, Giovanni B. ;
Alessandrini, Fabrizio ;
Passerini, Stefano .
JOURNAL OF POWER SOURCES, 2007, 171 (02) :861-869
[88]   Effects of imidazolium salts on discharge performance of rechargeable lithium-sulfur cells containing organic solvent electrolytes [J].
Kim, S ;
Jung, YJ ;
Park, SJ .
JOURNAL OF POWER SOURCES, 2005, 152 (01) :272-277
[89]   Effects of Nano Alumina and Plasticizers on Morphology, Ionic Conductivity, Thermal and Mechanical Properties of PEO-LiCF3SO3 Solid Polymer Electrolyte [J].
Klongkan, Sasithorn ;
Pumchusak, Jantrawan .
ELECTROCHIMICA ACTA, 2015, 161 :171-176
[90]   Fabrication and processing of polymer solar cells: A review of printing and coating techniques [J].
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (04) :394-412